3D porous metal-organic framework exhibiting selective adsorption of water over organic solvents |
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| Authors: | Gu Jin-Zhong Lu Wen-Guan Jiang Long Zhou Hong-Cai Lu Tong-Bu |
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| Affiliation: | MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China. |
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| Abstract: | A 3D porous metal-organic framework (MOF) with 1D open channels has been constructed hydrothermally using Zn(II) and a rigid planar ligand IDC(3)- (imidazole-4,5-dicarboxylate). This MOF can adsorb water selectively over organic solvents and can be regenerated and reused. It also represents a rare example of a MOF with open channels that form/collapse reversibly upon hydration/dehydration. |
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