Oxidation of organic substances with compounds of trivalent manganese: XXIII. Preparation,stability, and determination of the titer of standard solutions of the fluoride complex of trivalent manganese |
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Authors: | J. Barek A. Berka H. Skokánková |
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Affiliation: | Department of Analytical Chemistry, Charles University, Albertov 2030, 128 40 Prague 2, Czechoslovakia |
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Abstract: | A method of preparation of 10?2 ?10?3M standard solutions of the fluoride complex of manganese(III) by the reaction of manganese(II) with permanganate in a medium of potassium fluoride acidified with sulfuric acid has been developed. It has been found that in a medium of 1 M sulfuric acid, 0.5 M manganese(II) sulfate, and 0.1 M potassium fluoride these solutions are sufficiently stable for both direct and indirect titrimetric determinations. The titer was determined using potassium iodide as a primary standard and potentiometric, bipotentiometric, or biamperometric titration. |
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