Abstract: | Phase-transfer catalysis and template assembly on sodium and cesium cations were used to prepare 2-(diphenylphosphoryl)phenyl ethers of ethylene glycols Ln with varied number of polyether units (n = 3–8). Previously unknown dinitro and disulfo derivatives of 2-(diphenylphosphoryl)phenyl ethers of di- and triethylene glycols were synthesized. Complexes [NaL4]NCS·C6H6, [NaL4]ClO4, [KL5]NCS, and [KL5]ReO4 were synthesized, and their crystal structure was studied. Structure–stability constant correlations were found for alkali metal complexes with phosphoryl podands Ln and isodentate crown ethers. |