Side-effect of ancillary ligand on electron transfer and photodynamics of a dinuclear valence tautomeric complex |
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| Authors: | Li Bao Tao Jun Sun Hao-Ling Sato Osamu Huang Rong-Bin Zheng Lan-Sun |
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| Affiliation: | State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, Xiamen University, Xiamen 361005, People's Republic of China. |
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| Abstract: | A cobalt complex [[Co(dpqa)]2(dhbq)](PF6)3 ((PF6)3, dhbq = deprotonated 2,5-dihydroxy-1,4-benzoquinone, dpqa = di(2-pyridylmethyl)-N-(quinolin-2-ylmethyl)amine) was prepared and studied by X-ray diffraction, electrochemistry, ESR, thermally and photo-induced magnetic measurements; the results show that the ancillary ligand finely tuned structural factors as well as intermolecular interactions that affect the VT behavior. |
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