| 树枝状共轭聚合物研究 |
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| 引用本文： | 张璐,封伟.树枝状共轭聚合物研究[J].化学进展,2007(Z1). |
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| 作者姓名： | 张璐 封伟 |
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| 作者单位： | 天津大学材料科学与工程学院 天津300072 |
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| 基金项目： | 国家自然科学基金项目(No.60307001,50573057)，天津市自然科学基金项目(No.05YFJMJC08800)资助 |
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| 摘 要： | 本文介绍了树枝状共轭聚合物的最新发展,包括全共轭、部分共轭树枝状聚合物及树枝化共轭聚合物的特点及其在电致发光、电极、传感器以及光探测等领域的功能化应用;详细讨论了包括代数、支化单元、端基、核、金属离子的络合等结构因素以及溶剂和浓度等工艺因素对电荷传输的影响;并进一步提出该领域研究前景及有待于解决的问题。
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| 关 键 词： | 树枝状 超支化 共轭聚合物 树枝状聚合物 电导率 |
Dendritic Conjugated Polymers |
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| Zhang Lu Feng Wei.Dendritic Conjugated Polymers[J].Progress in Chemistry,2007(Z1). |
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| Authors: | Zhang Lu Feng Wei |
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| Institution: | Zhang Lu Feng Wei~ |
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| Abstract: | This paper systematically introduces the development of dendritic conjugated polymers including the characteristics and functionalized application of full-conjugated dendritic polymers,partial-conjugated dendritic polymers and dendrinized conjugated polymers in organic light emitting diode(OLED),electrode,sensor,and light-harvesting systems etc.It summarizes the affecting factors on the optical and electrical properties of dendritic conjugated polymers including the structure factors containing the generation factor,the scaffolding factor,the periphery factor,the core factor,the metallic ion factor etc.and the technology factors such as the solvent and the concentration factors.Additionally,the perspectives and the problems should be solved in the future are provided. |
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| Keywords: | dendritic hyperbranched conjugated dendritic polymers dendrimers conductivity |
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