Synthesis and crystal structure of triphenyl[tris(tetrahydrofuran)]ytterbium, Ph3Yb(THF)3 |
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| Authors: | L. N. Bochkarev T. A. Zheleznova A. V. Safronova M. S. Drozdov S. F. Zhil'tsov L. N. Zakharov G. K. Fukin S. Ya. Khorshev |
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| Affiliation: | (1) Nizhnii Novgorod State Pedagogical University, 1 ul. Ul'yanova, 603600 Nizhnii Novgorod, Russian Federation;(2) G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603600 Nizhnii Novgorod, Russian Federation |
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| Abstract: | Triphenyl[tris(tetrahydrofuran)]ytterbium, Ph3Yb(THF)3 (1), was synthesized in high yields by the reaction of Yb with an excess of Ph2Hg or Ph3Bi in the presence of catalytic amounts of YbI2(THF)4 as well as by the reaction of Ph2Yb(THF)2 (2) with Ph2Hg or Ph3Bi. The crystal structure of complex1 was studied by X-ray structural analysis. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 163–166, January, 1998. |
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| Keywords: | ytterbium, redox reactions phenyl derivatives, X-ray structural analysis |
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