| DMF和DMSO配位的金属十聚钨酸盐在非水溶剂中光致变色性质的研究 |
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| 引用本文： | 朱思三,岳斌,万国江,施晓群,顾翼东. DMF和DMSO配位的金属十聚钨酸盐在非水溶剂中光致变色性质的研究[J]. 应用化学, 1992, 0(3): 41-45 |
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| 作者姓名： | 朱思三 岳斌 万国江 施晓群 顾翼东 |
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| 作者单位： | 复旦大学化学系, 上海 200433 |
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| 摘 要： | 研究了某些DMF和DMSO配位的金属十聚钨酸盐在 3 种有机溶剂中的光致变色性质,通过ESR、NMR和可见吸收光谱的研究及对五价钨的测定,说明了光致变色性质的产生与金属阳离子无关,而取决于十聚钨酸根W10O324-、金属离子的配体及所采用溶剂。
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| 关 键 词： | 配合物 十聚钨酸盐 DMSO DMF 光致变色 五价钨 |
| 收稿时间： | 1991-03-05 |
| 修稿时间： | 1991-10-10 |
ON PHOTOCHROMISM OF DMF AND DMSO COORDINATED METAL DECATUNGSTATES IN NON-AQUEOUS SOLVENTS |
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| Zhu Sisan,Yue Bin,Wan Guojiang,Shi Xiaoqun,Gu Yidong. ON PHOTOCHROMISM OF DMF AND DMSO COORDINATED METAL DECATUNGSTATES IN NON-AQUEOUS SOLVENTS[J]. Chinese Journal of Applied Chemistry, 1992, 0(3): 41-45 |
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| Authors: | Zhu Sisan Yue Bin Wan Guojiang Shi Xiaoqun Gu Yidong |
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| Affiliation: | Department of Chemistry, Fudan University, Shanghai 200433 |
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| Abstract: | The photochromism of some DMF and DMSO coordinated metal decatungstates in DMF DMSO, and acetonitrile has been studied through ESR, 1H NMR, risible spectra and W(Ⅴ) determination. The photochromism is found mainly to be related to the decatungstate W10O324-, the ligands coordinated with metal ions and the solvents used. |
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| Keywords: | decatungstate coordinated compound DMF DMSO photochromism tungsten(Ⅴ) |
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