Correlation between adsorption and thermal properties of lanthanide(III) dinicotinates |
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| Authors: | R ?yszczek |
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| Institution: | Department of General and Coordination Chemistry, Faculty of Chemistry, Maria Curie-Sk?odowska University, Sq. M.C. Sk?odowskiej 2, 20-031 Lublin, Poland |
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| Abstract: | Structural and thermal properties of the two isostructural lanthanide metal-organic frameworks: Er2(pdc)3(dmf)2]·dmf (1) and Tm2(pdc)3(dmf)2]·dmf (2) where pdc = C5H3N(COO)22− and dmf = N,N′-dimethylformamide, have been investigated. They are characterized by the BET surface area of 302 and 101 m2/g for 1 and 2, respectively. This paper deals with the influence of activation conditions on sorption properties of the investigated complexes. Thermal investigations of as-made and activated complexes point to their entirely different thermal decompositions. |
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| Keywords: | Lanthanides Metal complexes Thermal analysis Adsorption |
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