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Passivation of aluminum with alkyl phosphonic acids for biochip applications
Authors:Sachin Attavar  Matthew R Linford  Steve Blair
Institution:a Department of Electrical Engineering, University of Utah, 50 South Central Campus Drive, Salt Lake City, UT 84112, United States
b Department of Chemistry and Biochemistry, Brigham Young University, Provo, UT 84602, United States
c MOXTEK Inc, 452 West 1260 North, Orem, UT 84057, United States
Abstract:Self-assembly of decylphosphonic acid (DPA) and octadecylphosphonic acid (ODPA) was studied on aluminum films using XPS, ToF-SIMS and surface wettability. Modified aluminum films were tested for passivation against silanization and subsequent oligonucleotide attachment. Passivation ratios of at least 450:1 compared to unprotected aluminum were obtained, as quantified by attachment of radio-labeled oligos.
Keywords:Biosenor  DNA metallic microarray  Phosphonic acid self-assembled monolayer
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