Deoxygenation of dithiirane 1-oxides with Lawesson's reagent leading to the corresponding dithiiranes |
| |
Authors: | Ishii Akihiko Yamashita Remi Saito Masashi Nakayama Juzo |
| |
Affiliation: | Department of Chemistry, Faculty of Science, Saitama University, Japan. ishiiaki@chem.saitama-u.ac.jp |
| |
Abstract: | 3,3-Disubstituted dithiirane 1-oxides were efficiently reduced with Lawesson's reagent (LR) to give the corresponding dithiiranes. X-ray diffraction analysis of 3,3-di(1-adamantyl)dithiirane is reported. Reaction of (34)S-labeled 3,3-di(1-adamantyl)dithiirane 1-oxide with LR produced the corresponding dithiirane in which the (34)S atoms were retained quantitatively. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|