Facile palladium(0)-catalyzed ring expansion reactions of hydroxy methoxyallenyl cyclic compounds via hydropalladation |
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Authors: | Nagao Yoshimitsu Ueki Akiharu Asano Kazunori Tanaka Satoru Sano Shigeki Shiro Motoo |
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Institution: | Faculty of Pharmaceutical Sciences, The University of Tokushima, Sho-machi, Tokushima 770-8505, Japan. ynagao@ph2.tokushima-u.ac.jp |
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Abstract: | Palladium(0)-catalyzed one-atom ring expansion of various hydroxy methoxyallenyl compounds has been achieved in excellent yields without the use of aryl halides. Hydroxy methoxyallenylisoindolinones, -indanones, and -phthalans have been readily converted to the corresponding isoquinolones, naphthoquinones, and isochromanones in the presence of P(o-tolyl)(3). |
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