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Diels-Alder-Reaktion eines elektronenarmen C-Acylimins mit Tetraethoxyethylen
Authors:M Felderhoff  R Sustmann
Institution:(1) Institut für Organische Chemie, Universität GH Essen, D-45117 Essen, Deutschland
Abstract:Summary The synthesis of two C-acylimines and their reactivity towards electron rich dienophiles inDiels-Alder reactions is described. A 4+2] cycloadduct is obtained only in one case: from the reaction of a C-acylimine substituted by two methoxycarbonyl groups with tetraethoxyethylene. No 2+2] cycloadducts are observed.
Keywords:C-Acylimine  Diels-Alder Reaction  [4+2] Cycloaddition  1  4-Oxazine
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