Asymmetric nitrogen |
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| Authors: | A. V. Prosyanik V. V. Rozhkov A. S. Moskalenko A. I. Mishchenko A. Forni I. Moretti G. Torre S. Brukner L. Malpezzi R. G. Kostyanovsky |
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| Affiliation: | 1. Ukrainian State University of Chemistry and Technology, 6 pros. Gagarina, 32005, Dnepropetrovsk, Ukraine
2. N. N. Semenov Institute of Chemical Physics, Russian academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation
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| Abstract: | The possibility of tranferring chirality from nitrogen to carbon by a three-step transformation of racemic dimethyl 1-methoxyaziridine-2,2-dicarboxylate into 3-amino-2-chloromethyl-2-methoxyaminopropan-1-ol was demonstrated. The first representative of 1-silyloxyaziridines,viz., dimethyl 1-(tert-butyldimethylsilyloxy)aziridine-2,2-dicarboxylate, was synthesized by acidolysis or thermolysis of triazoline, obtained by the reaction oftert-butyldimethylsilyloxime of dimethy mesoxalate with CH2N2 |
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