| 摘 要： | A new cadmium(II) coordination polymer with unique structure was synthesized under diffusion process by employing triangular N-containing ligand tris(4-(pyridyl) phenyl) amine(Tppa). Complex 1 crystallizes in the space group Pbcn, with a = 28.906(3), b = 13.5294(14), c = 17.8727(18), V = 6989.7(12) 3, C66H48 Cd Cl2N8, Mr = 1136.42, Dc = 1.080 g/cm3, F(000) = 2328, μ = 0.428 mm-1 and Z = 4. Complex 1 features a 2D → 3D framework with the coexistence of inclined polycatenation and polythreading. In addition, the luminescent property of complex 1 was studied.
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