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Transformations of Isocaryophyllene Diepoxide under Conditions of Homogeneous and Heterogeneous Acid Catalysis |
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| Authors: | O V Salomatina O I Yarovaya D V Korchagina Yu V Gatilov M P Polovinka V A Barkhash |
| Institution: | (1) Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia;(2) Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 9, Novosibirsk, 630090, Russia |
| Abstract: | Transformations of isocaryophyllene diepoxide (an isomer of widely spread natural sesquiterpene) were studied in various acidic media under conditions of homogeneous and heterogeneous catalysis. A number of previously unknown compounds were thus obtained. The experimental data were compared with the results of molecular-mechanics and quantum-chemical simulation of the most probable transformation paths. |
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