Stereoselective synthesis of the polyketide chain of nagahamide A |
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| Institution: | 1. College of Chemistry, Key Lab of Environment-Friendly Chemistry and Application in Ministry of Education, Xiangtan University, Xiangtan, 411105, China;2. State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhouv, 510640, China;3. School of Materials Science and Engineering, Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, Changzhou University, Changzhou, 213164, China;1. Université de Tunis El Manar, Faculté des Sciences de Tunis, Laboratoire de Synthèse Organique et Hétérocyclique, 2092 Tunis, Tunisia;2. Université de Versailles Saint Quentin-en-Yvelines, Institut Lavoisier de Versailles-UMR CNRS 8180, 45 avenue des Etats-Unis, 78035 Versailles, France;1. Institute for Nanoscience and Nanotechnology, Sharif University of Technology, 11365-8639 Tehran, Iran;2. Department of Materials Science and Engineering, Missouri University of Science and Technology, 1400N. Bishop Avenue, Rolla, MO 65409-0340, USA;3. Department of Materials Science and Engineering, Sharif University of Technology, 1458889694 Tehran, Iran;1. Normandie Univ, UNIROUEN, INSA Rouen, CNRS, COBRA (UMR 6014), 76000 Rouen, France;2. Taras Shevchenko National University of Kyiv, 64/13 Volodymyrska Street, 01601 Kyiv, Ukraine;3. Université de Reims Champagne-Ardenne, UMR CNRS 7312, 51687 Reims cedex 2, France |
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| Abstract: | A carbohydrate based approach for the enantioselective synthesis of the polyketide acid unit present in nagahamide A has been reported. Reductive ring opening of a chiral cyclopropane ketone group to enantioselectively install the methyl and propyl groups, is a salient feature of this synthesis. |
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