Synthesis of a Schiff’s base chiral ligand with a trifluoromethyl carbinol moiety |
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| Affiliation: | 1. School of Chemistry and Center of Excellence for Innovation in Chemistry, Institute of Science, Suranaree University of Technology, Muang District, Nakhon Ratchasima 30000, Thailand;2. Department of Chemistry, Faculty of Science, Ubon Ratchathani University, Ubon Ratchathani 34190, Thailand;3. National Nanotechnology Center (NANOTEC), 130 Thailand Science Park, Klong Luang, Pathumthani 12120, Thailand;4. PTT Group Frontier Research Center, PTT Public Company Limited, 555 Vibhavadi Rangsit Road, Chatuchak, Bangkok 10900, Thailand;1. Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, Shandong, People’s Republic of China;2. University of Chinese Academy of Sciences, Beijing 100049, People’s Republic of China;3. School of Science, Department of Chemistry, Xi’an Jiaotong University, Xi’an 710049, People’s Republic of China;4. Key Laboratory of Theoretical and Computational Photochemistry, Ministry of Education, College of Chemistry, Beijing Normal University, Beijing 100875, People’s Republic of China |
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| Abstract: | A Schiff’s base ligand with a trifluoromethyl carbinol moiety was synthesized, and a structure of the active complex for asymmetric induction on the reaction of diethylzinc with aldehydes is proposed. |
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