A short and efficient synthesis of (R)-(−)-sporochnol A |
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| Institution: | 1. Federal University of Rio Grande do Sul (UFRGS), Engineering School, Laboratory of Polymeric Materials (LAPOL), P.O. Box 15010, 91501-970 Porto Alegre, Brazil;2. University of Birmingham, Chemical Engineering School, B15 2TT Birmingham, England, United Kingdom;3. HySA Systems Competence Centre, SAIAMC, University of the Western Cape, Private Bag X17, Bellville 7535, Cape Town, South Africa |
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| Abstract: | A short and efficient synthesis of (R)-(−)-sporochnol A in five steps and 9% overall yield has been developed. The sequence uses as starting material the easily available enantiopure monoketal derived from 1,4-cyclohexanedione and (R,R)-hydrobenzoin that serves as a chiral auxiliary. |
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