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Solid state imposed vibrational coupling between nu1 and nu3 modes of tetrahedral ions
Authors:Aljowder Osama Abdulla
Institution:Department of Chemistry, College of Science, University of Bahrain, Isa Town, Bahrain. osamajdr@sci.uob.bh
Abstract:Raman spectra of the thiomolybdate ion in the compounds Cu.NH4]MoS4] and X2MoS4], where X=NH4+, Rb+ or Cs+, are reported and used to confirm the hypothesis presented in an earlier paper J. Chem. Phys. 94 (1991) 5946], that there is solid state induced vibrational coupling between the nu1 and nu3 modes of tetrahedral ions.
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