| Gallery-templated Synthesis of Titanium／Silicon -containing Mesoporous Montmorillonite-based Catalytic Materials |
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| 引用本文： | ChunHuiZHOU ZhongHuaGE XiaoNianLI HongQiangGUO JianSUN. Gallery-templated Synthesis of Titanium／Silicon -containing Mesoporous Montmorillonite-based Catalytic Materials[J]. 中国化学快报, 2003, 14(12): 1285-1288 |
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| 作者姓名： | ChunHuiZHOU ZhongHuaGE XiaoNianLI HongQiangGUO JianSUN |
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| 作者单位： | CollegeofChemicalEngineering,ZhejiangUniversityOfTechnology,Hangzhou310014 |
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| 基金项目： | 国家自然科学基金，Zhejiang Provincial Natural Science Foundation NSF |
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| 摘 要： | A mesoporous titanium/silicon -containing montmorillonite-based catalytic materials has been synthesized by novel gallery-templated techniques. XRD, SEM, framework IR, and N2 adsorption-desorption isotherms provided evidence of the formation of Si/Ti pillars. The synthetic materials show potential catalytic application for hydroxylation of phenol with peroxide.
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| 关 键 词： | 模板合成 钛／硅 分子筛 中孔材料 蒙脱石 催化剂 催化活性 柱状粘土 羟基化作用 苯酚 |
Gallery-templated Synthesis of Titanium/ Silicon -containing Mesoporous Montmorillonite-based Catalytic Materials |
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| Chun Hui ZHOU,Zhong Hua GE,Xiao Nian LI,Hong Qiang GUO,Jian Sun. Gallery-templated Synthesis of Titanium/ Silicon -containing Mesoporous Montmorillonite-based Catalytic Materials[J]. Chinese Chemical Letters, 2003, 14(12): 1285-1288 |
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| Authors: | Chun Hui ZHOU Zhong Hua GE Xiao Nian LI Hong Qiang GUO Jian Sun |
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| Abstract: | A mesoporous titanium/silicon -containing montmorillonite-based catalytic materials has been synthesized by novel gallery-templated techniques. XRD, SEM, framework IR, and N2 adsorptiondesorption isotherms provided evidence of the formation of Si/Ti pillars. The synthetic materials show potential catalytic application for hydroxylation of phenol with peroxide. |
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| Keywords: | Mesoporous materials montmorillonite pillared clay hydroxylation of phenol. |
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