A zeolitic organo-metallophosphate hybrid material with bimodal porosity |
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| Authors: | Liao Yueh-Chun Liao Fen-Ling Chang Wei-Kuo Wang Sue-Lein |
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| Institution: | Department of Chemistry, National Tsing Hua University, Hsinchu 30043, Taiwan. |
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| Abstract: | The first metal carboxylatophosphate, NTHU-2, contains inorganic ZnHPO4 layers linked by BDC units (BDC = 1,4-benzene dicarboxylate or terephthalic anion); the three-dimensional anionic framework has large pores with the smallest diameter being 1.36 nm; N2 sorption isotherms reveal both micro- and mesoporosity; the new material is photoluminescent and disassembles in water wherein the discharged organic fragments form mixed crystals. |
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