Synthesis,growth and characterization of hydrogen bonding organic complex for SHG conversion: 3-hydroxyanilinium-2,5-dimethylbenzenesulphonate single crystal |
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| Affiliation: | 1. Centre for Crystal Growth, SSN College of Engineering, Kalavakkam 603110, India;2. Department of Chemistry, SRMV College of Arts and Science, Coimbatore 20, India;3. X-ray Crystallography Laboratory, Post-Graduate Department of Physics, University of Jammu, Jammu Tawi 180 006, India;1. Graduate School of Engineering, University of Fukui, Bunkyo 3-9-1, Fukui 910-8507, Japan;2. Toyo University, 2100 Kujirai, Kawagoe, Saitama 350-8585, Japan;3. National Institute for Materials Science (NIMS), Sengen 1-2-1, Tsukuba, Ibaraki 305-0047, Japan;1. Department of Physics, Amrita Vishwa Vidyapeetham, Kollam - 690525, Kerala, India;2. Department of Sciences, Amrita Vishwa Vidyapeetham, Coimbatore 641 112, Tamil Nadu, India;3. Department of Physics, Govt. College, Kottayam - 686013, Kerala, India;1. Department of Physics, TKM College of Arts and Science, Kollam, Kerala, India;2. Department of Physics, Fatima Mata National College, Kollam, Kerala, India;3. Department of Medical Chemistry, Medical University of Warsaw, Oczki 3, 02-007 Warszawa, Poland;4. Department of Chemistry, University of Antwerp, B2610 Antwerp, Belgium;5. Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia |
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| Abstract: | The new hydrogen bonding single crystal of 3-hydroxyanilinium-2,5-dimethylbenzenesulphonate (3HADB) complex has been synthesized and grown by slow evaporation solution growth technique. The grown crystal was confirmed by single crystal X-ray diffraction, Fourier Transform Infrared (FT-IR) and proton Nuclear Magnetic Resonance (1HNMR) spectral studies. Single crystal X-ray diffraction study shows that 3HADB crystallizes in the orthorhombic crystal system with noncentrosymmetric Pna21 space group. The title compound was characterized by UV–Vis–NIR absorption and TG/DTA thermal analysis studies. The second harmonic generation efficiency of powdered 3HADB was determined by Kurtz and Perry method. |
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