Preparation and characterization of unique inorganic-organic hybrid mesoporous materials incorporating arenetricarbonyl complexes [-C6H4M(CO)3-] (M = Cr, Mo) |
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| Authors: | Kamegawa Takashi Sakai Takahiro Matsuoka Masaya Anpo Masakazu |
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| Institution: | Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Japan. |
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| Abstract: | Unique inorganic-organic hybrid mesoporous materials incorporating arenetricarbonyl complexes -C6H4M(CO)3-] (M = Cr, Mo) within their mesoporous frameworks have been successfully prepared by a simple CVD treatment of the phenylene-bridged organosilica mesoporous materials with metal hexacarbonyls M(CO)6] (M = Cr, Mo). FT-IR and UV-vis investigations revealed that the arenetricarbonyl complexes exist stably even at temperatures above 473 K under vacuum. |
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