The Effect of 19-Substituent on the Stereospecific Hydroxylation of △^5-Steroids Using Performic Acid as Oxidant |
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作者姓名: | WeiGangLU JingYuSU LongMeiZENG HongLI |
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作者单位: | SchoolofChemistryandChemicalEngineering,SunYat-sen(zhongshan)University,Guangzhou510275 |
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摘 要: | In the studying of the stereospecific hydroxylation of different △^5-steroids with performic acid, followed by hydrolysis with CH3OH/KOH, we found 19-substituting groups considerably affected the reaction and we put forward the mechanism.
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关 键 词: | 19-取代群 立体选择性 羟基化作用 △^5-类固醇 过甲酸 氧化剂 |
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