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The Effect of 19-Substituent on the Stereospecific Hydroxylation of △^5-Steroids Using Performic Acid as Oxidant
作者姓名:WeiGangLU  JingYuSU  LongMeiZENG  HongLI
作者单位:SchoolofChemistryandChemicalEngineering,SunYat-sen(zhongshan)University,Guangzhou510275
摘    要:In the studying of the stereospecific hydroxylation of different △^5-steroids with performic acid, followed by hydrolysis with CH3OH/KOH, we found 19-substituting groups considerably affected the reaction and we put forward the mechanism.

关 键 词:19-取代群  立体选择性  羟基化作用  △^5-类固醇  过甲酸  氧化剂
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