Comparative analysis of shape memory-based self-healing coatings

Self-healing materials exhibit the ability to repair and to recover their functionality upon damage. Here, we report on an investigation into preparation and characterization of shape memory assisted self-healing coatings. We built on past work in which poly(ε-caprolactone) electrospun fibers were infiltrated with a shape memory epoxy matrix and delve into fabricating and characterizing a coating with the same materials, but employing a blending approach, polymerization induced phase separation. After applying controlled damage, the ability of both coatings to self-heal upon heating was investigated. In both methods, coatings showed excellent thermally induced crack closure and protection against corrosion, with the blend approach being more suitable for large-scale applications given its process simplicity. Two different approaches to the preparation of shape memory-based self-healing coatings were compared for their ability to heal structurally and functionally by heating. These two approaches, electrospinning versus polymerization-induced phase separation were found to feature comparable and quite complete healing, with the latter system offering the advantage of facile processing. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1415–1426