Palladium‐Catalyzed Enantioselective C?H Arylation for the Synthesis of P‐Stereogenic Compounds |
| |
Authors: | Zi‐Qi Lin Wei‐Zhen Wang Shao‐Bai Yan Wei‐Liang Duan |
| |
Abstract: | A palladium‐catalyzed enantioselective C H arylation of N‐(o‐bromoaryl)‐diarylphosphinic amides is described for the synthesis of phosphorus compounds bearing a P‐stereogenic center. The method provides good enantioselectivities and high yields. The products were readily transformed into P‐chiral biphenyl monophosphine ligands. |
| |
Keywords: | Asymmetrische Katalyse C‐H‐Aktivierung Chiralitä t Palladium P‐Liganden |
|