Synthesis of electron beam cured free‐standing ion‐gel membranes for organic electronics applications |
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| Authors: | Marco Mennillo Yanxi Zhang Fredrik Pettersson Carl‐Johan Wikman Tommi Remonen Ronald Österbacka Carl‐Eric Wilén |
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| Affiliation: | 1. Faculty of Science and Engineering/Chemical Engineering/Polymer Technology and Center for Functional Materials, ?bo Akademi University, Turku, Finland;2. Faculty of Science and Engineering/Natural Sciences/Physics and Center for Functional Materials, ?bo Akademi University, Turku, Finland |
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| Abstract: | Cost efficient and facile synthesis of functional materials that enable low voltage operations is highly demanded for the future growth of plastic electronic sector. In this article we report a fast, solvent‐free and roll‐to‐roll compatible method of fabricating novel solid ion‐gel membranes from 1‐ethyl‐3‐methylimidazolium bis(trifluoromethyl‐sulfonyl)imide ([EMIM][TFSI]) and acrylate monomer blends of trimethylolpropane triacrylate (TMPTA) and tetra(ethylene glycol)diacrylate (TEDGA) via electron beam curing. The manufactured free standing and solid ion‐gel membranes were successfully utilized in various electronic devices such as ion‐modulated organic thin film transistors (IMTs), supercapacitors (SC) and electrochromic (EC) displays. The tailor‐made ion‐gel membrane, with an optimized composition, exhibited high specific capacitance and good mechanical properties. The prepared IMTs operated at remarkable low voltages of less than 1.5 V with on‐currents on the order of milliamps and ON/OFF ratios greater than ～104. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 2352–2360 |
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| Keywords: | electron beam electrochromic display free‐standing ion‐gel ionic liquid ion‐modulated thin‐film transistor printed electronics supercapacitor |
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