Study of the composition and morphology of new modifications of titanium‐magnesium catalysts with improved properties in ethylene polymerization |
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| Authors: | Tatiana B Mikenas Evgeny I Koshevoy Svetlana V Cherepanova Vladimir A Zakharov |
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| Institution: | 1. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia;2. Novosibirsk State University, Novosibirsk, Russia |
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| Abstract: | Data on new modifications of supported titanium‐magnesium catalysts (TMCs) with improved performance in ethylene polymerization are reported. These catalysts possess a high and stable activity, an enhanced ability to regulate molecular weight of the polymer by hydrogen, a controllable particle size at a narrow particle size distribution, and the ability to produce the polymer with an increased bulk density. Various physicochemical methods were used to obtain data on the chemical composition of novel supports and catalysts, their phase composition and crystal structure as well as the pore structure. The results obtained were used to discuss possible correlations between composition and structure of TMCs and their catalytic properties. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 2545–2558 |
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| Keywords: | crystal structures polyethylene (PE) pore structure structure‐property relations Ziegler‐Natta polymerization |
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