Simulation of pulse responses of lithium salt‐doped poly ethyleneoxide |
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Authors: | Ao Liu Fei Zeng Yuandong Hu Siheng Lu Wenshuai Dong Xiaojun Li Chiating Chang Dong Guo |
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Institution: | 1. Laboratory of Advanced Materials (MOE), School of Materials Science and Engineering, Tsinghua University, Beijing, People's Republic of China;2. Center for Brain Inspired Computing Research (CBICR), Tsinghua University, Beijing, People's Republic of China;3. School of Materials Sciences & Engineering, Beihang University, Beijing, People's Republic of China |
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Abstract: | Ionic migration in organic electrolytes resembles that in neural system involving signal transportation. Here, ionic dynamic simulations are applied to explore pulse responses of lithium‐doped polyethyleneoxide complexes. Two main interactions were considered: diffusion of ions and directional movement guided by an applied electric field. Frequency responses are simulated using arbitrary wave shape. It is found that redistribution of ions results in accumulation of charge and establishes a reverse inbuilt electric field controlling the discharging process and the frequency response. The charging current's wave shape is controlled mainly by contribution from the diffusion process, which strengthens the charging current in the first millisecond before weakening it. For stimulation with higher energy density (higher frequency), activation of ion channels should be considered and an active ion number is introduced to describe the process. The weights of calculated discharging current agree well with the experimental results. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 831–837 |
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Keywords: | fast ionic conductor frequency selectivity macromolecules polyethyleneoxide |
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