| 氯柱硼镁石在盐酸溶液中溶解及相转化平衡溶液的振动光谱分析 |
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| 引用本文： | 高 波,刘志宏,李淑妮,胡满成,夏树屏.氯柱硼镁石在盐酸溶液中溶解及相转化平衡溶液的振动光谱分析[J].无机化学学报,2003,19(9):1015-1018. |
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| 作者姓名： | 高 波 刘志宏 李淑妮 胡满成 夏树屏 |
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| 作者单位： | 1. 陕西师范大学化学与材料科学学院,西安,710062
2. 中国科学院盐湖研究所西安二部,西安,710043 |
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| 基金项目： | 国家自然科学基金资助项目(No.20271051)。 |
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| 摘 要： | The FT-IR difference spectroscopy and the Raman spectroscopy were used to identify the polyborate ions in saturated aqueous solutions during dissolution and transformation of 2MgO·2B2O3·MgCl2·14H2O in different HCl solutions at 30℃. The assignments of the recorded IR-Spectroscopic frequencies and Raman shift of the borate aqueous solution are given. The existing forms of polyborate anions in saturated aqueous solution and their inter-action have been discussed. The relationships between the existing forms of polyborate anions and the crystallizing solid phases have been gained.
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| 关 键 词： | 差示FT-IR光谱 Raman光谱 饱和硼酸盐溶液 氯柱硼镁石 盐酸 |
Vibrational Spectroscopic Analysis of Saturated Borate Aqueous Solution of Chloropinnoite in HCl(aq) |
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| GAO Bo,LIU Zhi-Hong,LI Shu-Ni,HU Man-Cheng and XIA Shu-Ping.Vibrational Spectroscopic Analysis of Saturated Borate Aqueous Solution of Chloropinnoite in HCl(aq)[J].Chinese Journal of Inorganic Chemistry,2003,19(9):1015-1018. |
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| Authors: | GAO Bo LIU Zhi-Hong LI Shu-Ni HU Man-Cheng and XIA Shu-Ping |
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| Abstract: | |
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| Keywords: | FT-IR difference spectra Raman spectra saturated borate solution chloropinnoite hydrochloric acid |
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