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Peak shapes of acids and bases under overloaded conditions in reversed-phase liquid chromatography,with weakly buffered mobile phases of various pH: A thermodynamic interpretation |
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| Authors: | Fabrice Gritti Georges Guiochon |
| Affiliation: | 1. Department of Chemistry, University of Tennessee, Knoxville, TN 37996-1600, USA;2. Division of Chemical Sciences, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6120, USA |
| Abstract: | |
| Keywords: | Overloaded band profiles Acids and bases compounds C18 reversed-phase columns Weak buffer capacity Nonlinear chromatography Competitive adsorption isotherms Column heterogeneity Silanol activity Silica |
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