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Effects of synthesis conditions on the electrochemical activity of titanium anodes with iridium oxide coating
Authors:I. A. Velikanova  N. P. Ivanova  I. M. Zharskii
Affiliation:(1) Belarus State Technological University, ul. Sverdlova 13a, Minsk, 220050, Belarus
Abstract:The effects of temperature, heat treatment time, and iridium content in the active layer on the electrocatalytic activity of titanium anodes with active coating during oxygen evolution in 0.5 M sulfuric acid have been investigated. The highest activity of these electrodes is reached when the temperature of final treatment is 450°C, treatment time is 25 min, and iridium content in the active layer is over 2 g/cm2. An X-ray photoelectron spectroscopy study showed that iridium is predominantly in the tetravalent oxidized state in the active layer.
Keywords:coatings  iridium oxides  titanium anode  anode polarization  electrocatalytic activity  thermal treatment
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