| Synthesis and Crystal Structure of a Chiral Manganese(Ⅲ) Schiff Base Complex |
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| 引用本文： | 陈东波,盛天录,王欣,陈建珊,胡胜民,傅瑞标,沈超君,邹青竹,吴新涛.Synthesis and Crystal Structure of a Chiral Manganese(Ⅲ) Schiff Base Complex[J].结构化学,2010,29(3):471-475. |
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| 作者姓名： | 陈东波 盛天录 王欣 陈建珊 胡胜民 傅瑞标 沈超君 邹青竹 吴新涛 |
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| 作者单位： | State;Laboratory;Structural;Chemistry;Fujian;Institute;Research;Structure;Matter;Chinese;Academy;Sciences;Graduate;School; |
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| 基金项目： | Supported by the 973 Program (2007CB815301 and 2006CB932904);;the National Natural Science Foundation of China (20333070, 20673118, 20871114);;the Science Foundation of CAS (KJCX2-YW-M05);;Fujian Province (2006J0014, 2006F3132) |
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| 摘 要： | A chiral salency complex,Mn(Salency)(H2O)2](PF6)·2H2O 1(Salency =(R,R)-N,N'-bis(salicylidene)-1,2-cyclohexanediamine),has been prepared by the reaction of Mn(CH3COO)3·2H2O with Salency and NH4PF6,and was established by X-ray diffraction techniques.The complex crystallizes in triclinic,space group P1 with a=9.299(8),b=10.012(8),c=13.461(11),α=92.037(15),β=92.974(12),γ=93.530(18)°,V=1248.3(18)3,C20H28F6MnN2O6P,Mr = 592.35,Z=2,Dc=1.038 g/cm3,F(000)=608,μ=0.676 mm-1,the final R=0.0651 and wR=0.1880 for 5260 observed reflections with I 2σ(I).
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