| 锰、铑原卟啉IX-二甲酯配合物共振拉曼光谱研究 |
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| 引用本文： | 高琳,敬永升,雷天乾,江天籁.锰、铑原卟啉IX-二甲酯配合物共振拉曼光谱研究[J].化学研究,1998,9(1):53-57. |
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| 作者姓名： | 高琳 敬永升 雷天乾 江天籁 |
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| 作者单位： | [1]河南纺织工业高等专科学校，郑州，450017 [2]开封医专药学系，开封，475001 [3]中原制药厂研究所，郑州，450066 [4]中国科学院兰州化学物理研究所，兰州730000 |
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| 摘 要： | 合成了MnPPCl,RhPPCl,RhPPN3,RhPP(CO)Cl四种配合物 (PP =ProtophyrinIXDimethy1Ester) ,用元素分析、红外吸收光谱及紫外吸收光谱确定了配合物的组成 ,测定了它们的共振拉曼光谱 ,对特征谱带进行了归属。分析了拉曼谱带和电子吸收谱带变化的原因 ,提出了谱带频率的变化受金属离子外层d电子和轴配体的影响。
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| 关 键 词： | 锰 铑 原卟啉IX-二甲酯 共振拉曼光谱 |
The Study of Mn(Ⅲ)、Rh(Ⅲ)Protoporphyrin IX-Dimethy1 Ester Complexes by Resonance Raman Spectroscopy |
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| Gao Lin.The Study of Mn(Ⅲ)、Rh(Ⅲ)Protoporphyrin IX-Dimethy1 Ester Complexes by Resonance Raman Spectroscopy[J].Chemical Research,1998,9(1):53-57. |
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| Authors: | Gao Lin |
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| Abstract: | Complexes of MnPPCl(PP=Protoporphyrin IX Dimethy1 Ester),RhPPCl,RhPPN 3, RhPP(CO)Cl were prepared.Besides,the paper gives a report of the investigations of EA,IR and UV that assigned their composition,resonance Raman Spectra (RRS) of these complexes were the empirical assignments for some of the stronger Raman bands of the Metalloporphyrins,and the frequencies of their structure sensitive bands and λ max of their electron absorption spectra bands.The results suggest that Metallo porphyrin structure sensitive bands and electron absorption spectra bands are effeced by metal ions'outer d electrons and axial coordinate group. |
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| Keywords: | manganese(Ⅲ) rhodium(Ⅲ) protoporphyrin IX-dimethy1 ester resonance raman spectra |
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