Trapping of a cycloheptatetraene in the reaction of atomic carbon with phenol |
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| Authors: | Fatma SevinIkay Sökmen Bülent DüzPhilip B Shevlin |
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| Institution: | a Department of Chemistry, Hacettepe University, Beytepe-Ankara 06532, Turkey
b Department of Chemistry, Auburn University, Auburn, AL 36849-5312, USA |
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| Abstract: | Reaction of atomic carbon with phenol generates tropone in a reaction postulated to proceed via the hydroxycycloheptatetraenes, which rearrange to tropone. When the hydroxyphenylcarbenes are generated by the C atom deoxygenation of the corresponding aldehydes, the meta and para isomers produce tropone; the ortho isomer does not. |
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