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The allomorphism of a photochromic diarylethene
Authors:Shou-Zhi PuFu-Shi Zhang  Fan SunRu-Ji Wang  Xin-Hong ZhouShek-Kiu Chan
Institution:a Department of Chemistry, Tsinghua University, Beijing 100084, China
b Faculty of Science and Technology, University of Macau, Macau 3001, China
Abstract:The photochromic diarylethene, 1,2-bis(2-methyl-5-(2,2′-dicyanovinyl)-thien-3-yl)perfluorocyclopentene (1a), was synthesized by a novel method. Two kinds of single crystals of the compound were obtained depending on the different recrystallization conditions and their structures were determined by X-ray crystallographic analysis. Allomorphism of the photochromic diarylethene was discovered. The compound underwent a photochromic reaction both in solution and in the single crystalline phase of the anti-parallel conformer.
Keywords:diarylethene  photochromic  allomorphism  X-ray crystallographic analysis
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