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The first benzodiazepine o-quinodimethane: generation and Diels-Alder reactions
Authors:Minothora PozarentziJulia Stephanidou-Stephanatou  Constantinos A. Tsoleridis
Affiliation:Department of Chemistry, Laboratory of Organic Chemistry, University of Thessaloniki, 54124, Macedonia, Greece
Abstract:7,8-Bis(dibromomethyl)-3-bromo-2,4-diphenyl-3H-benzodiazepine 1 was used as a precursor for the benzodiazepine o-quinodimethane 2, which was trapped by in situ reactions with dienophiles.
Keywords:benzodiazepines   o-quinodimethanes   Diels-Alder reactions
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