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Diastereoselective Pd/In bimetallic inter-intramolecular (class 2) cascade reactions of allenyl-imines and aryl iodides |
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| Authors: | Ian R CooperRonald Grigg Michaele J HardieWilliam S MacLachlan Visuvanathar SridharanWAnthony Thomas |
| Institution: | a Molecular Innovation, Diversity and Automated Synthesis (MIDAS)Centre, School of Chemistry, University of Leeds, Leeds LS2 9JT, UK b GlaxoSmithKline, New Frontiers Science Park (North), Third Avenue, Harlow, Essex CM19 5AW, UK |
| Abstract: | A new diastereoselective Pd/In bimetallic inter-intramolecular cascade reaction employing allenyl-sulfinimines and aryl iodides is described. The tert-butanesulfinyl chiral auxiliary affords chiral, highly substituted cis-pyrrolidines and piperidines. |
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