An expedient route to p-tert-butylthiacalix[4]arene 1,3-diethers via Mitsunobu reactions |
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Authors: | István Bitter Viktor Csokai |
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Institution: | Department of Organic Chemical Technology, Budapest University of Technology and Economics, H-1521 Budapest, Hungary |
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Abstract: | Regioselective distal dialkylation of p-tert-butylthiacalix4]arene with alcohols was performed under the Mitsunobu protocol using the DEAD/TPP system. The method provides a versatile tool for obtaining 1,3-diethers with different functional groups in the alkyl chains. |
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Keywords: | thiacalix[4]arenes O-alkylation Mitsunobu reaction |
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