Synthesis of bis(ethylenedithio)tetrathiafulvalene derivatives with metal ion ligating centres |
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| Authors: | Jon-Paul GriffithsR.James Brown Peter DayCraig J. Matthews Bertrand VitalJohn D. Wallis |
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| Affiliation: | a Department of Chemistry and Physics, The Nottingham Trent University, Clifton Lane, Nottingham NG11 8NS, UK
b The Royal Institution of Great Britain, 21 Albemarle Street, London W1S 4BS, UK |
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| Abstract: | The syntheses of eight derivatives of BEDT-TTF (ET) containing pyridine, 2,2′-bipyridine or 2,4′-pyridylpyrimidine binding sites on a side chain are reported, for use in the preparation of organic/inorganic hybrid materials. The intermediate hydroxyethyl derivative of BEDT-TTF is prepared in an efficient five-step procedure. |
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| Keywords: | organic conductors BEDT-TTF organosulfur donors |
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