Use of triarylstibines in C-arylation reactions |
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| Authors: | Dmitry V MoiseevVera A Morugova Alexey V Gushchin Victor A Dodonov |
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| Institution: | Organic Chemistry Department, Nizhnii Novgorod State University, Nizhnii Novgorod, 603950, Russian Federation |
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| Abstract: | A new catalytic system based on triarylstibines for C-arylation of unsaturated compounds is proposed. It was found for a model reaction, the C-arylation of methyl acrylate, that in the presence of equimolar amounts of peroxide and catalytic amounts of a palladium compound (4 mol%), triarylstibines can act as mild efficient arylating agents. |
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| Keywords: | antimony(III) arylation palladium |
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