Low temperature syntheses of thioketals from enol ethers and carbonyl compounds |
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Authors: | Arnaud MartelSopa Chewchanwuttiwong Gilles DujardinEric Brown |
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Affiliation: | Laboratoire de Synthèse Organique, UMR 6011 CNRS, Faculté des Sciences, Avenue Olivier Messiaen, F-72085 Le Mans Cedex 9, France |
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Abstract: | A dithioacetalisation procedure at low temperature using TMSOTf as the promoter is described. This method proved highly efficient for unprecedented transprotection of ketone enol ethers and was successfully applied to polyfunctional sensitive substrates. |
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Keywords: | thioacetals transprotection enol ethers TMSOTf |
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