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Low temperature syntheses of thioketals from enol ethers and carbonyl compounds
Authors:Arnaud MartelSopa Chewchanwuttiwong  Gilles DujardinEric Brown
Affiliation:Laboratoire de Synthèse Organique, UMR 6011 CNRS, Faculté des Sciences, Avenue Olivier Messiaen, F-72085 Le Mans Cedex 9, France
Abstract:A dithioacetalisation procedure at low temperature using TMSOTf as the promoter is described. This method proved highly efficient for unprecedented transprotection of ketone enol ethers and was successfully applied to polyfunctional sensitive substrates.
Keywords:thioacetals   transprotection   enol ethers   TMSOTf
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