Single-step conversion of N-benzyl, N-trityl and N-diphenylmethyl amines to t-butyl carbamates using polymethylhydrosiloxane |
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Authors: | S Chandrasekhar BNagendra BabuChRaji Reddy |
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Institution: | Indian Institute of Chemical Technology, 500007 Hyderabad, India |
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Abstract: | t-Butyl carbamates were obtained efficiently in high yields from the corresponding N-benzyl, N-trityl and N-diphenylmethyl precursors in a single-step reductive transformation employing polymethylhydrosiloxane and di-t-butyl dicarbonate under Pd(OH)2/C catalysis. |
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Keywords: | polymethylhydrosiloxane di-tert-butyl dicarbonate |
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