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Synthesis of phosphonocinnamic thioesters, substrate analogues of cinnamoyl-CoA reductase, a key enzyme in the lignification process |
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| Authors: | Caroline LapeyreFlorence Bedos-Belval Hubert Duran Michel BaltasLiliane Gorrichon |
| Institution: | SPCMIB, UMR CNRS 5068, Université Paul Sabatier, 118 route de Narbonne, 31062 Toulouse, France |
| Abstract: | The one-pot transesterification of diethylarylvinylphosphonates with N-acetylcysteamine has been achieved using phosphonochloridates as intermediates. Reaction of phosphonodiesters with (COCl)2 gave the corresponding chlorinated compounds, which were coupled with N-acetylcysteamine in presence of Et3N. |
| Keywords: | lignification thioesters phosphonothioesters cinnamoyl-CoA reductase |
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