The effect of 2,2-dicyanovinyl groups as electron acceptors in push-pull substituted oligo(1,4-phenylenevinylene)s |
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Authors: | Herbert Meier,Jü rgen GeroldDominic Jacob |
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Affiliation: | a Institute of Organic Chemistry, University of Mainz, Duesbergweg 10-14, 55099 Mainz, Germany b Nirmala College, Muvattupuzha, India |
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Abstract: | The newly synthesized oligo(1,4-phenylenevinylene) series 2a-d with bis(2-hexyloctyl)amino groups as electron donors and 2,2-dicyanovinyl groups as electron acceptors represents conjugated oligomers with strong push-pull effects. Due to the decrease of the intramolecular charge transfer with increasing numbers of repeat units (n=1-4), the long-wavelength transition shows a particularly great hypsochromic shift for the extension of the chromophore. |
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Keywords: | oligomers conjugation push-pull effect UV/vis spectra |
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