Building molecular-scale bridges having restricted rotation |
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| Authors: | Andrew C Benniston Anthony HarrimanPeiyi Li Craig A Sams |
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| Institution: | Molecular Photonics Laboratory, Bedson Building, School of Natural Sciences (Chemistry), University of Newcastle, Newcastle-upon-Tyne NE1 7RU, UK |
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| Abstract: | The synthesis is reported of a binuclear ruthenium(II) bis(2,2′:6′,2″-terpyridine) complex for which the polytopic ligand incorporates a central, torsionally-constrained biphenylene group. In principle, the dihedral angle between the two phenylene rings can be controlled by the length of the constraining strap. |
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