A new and efficient catalytic isomerization of cis- and trans-epoxides |
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| Authors: | Ching-Yu LoSitaram Pal Arjan OdedraRai-Shung Liu |
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| Affiliation: | Department of Chemistry, National Tsing-Hua University, Hsinchu, Taiwan 30043, ROC |
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| Abstract: | We report new ruthenium-catalyzed cis-trans isomerization of various functionalized epoxides. Enantiospecific isomerization of chiral epoxides is achieved without loss of enantiopurity, and epimerization occurs only at the epoxide carbon of the activating group. |
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