The effect of solvent on tetracene oxidation by singlet molecular oxygen (Δg): aspects of specific solvation |
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Authors: | Evgeny A. Venedictov Elena J. Tulikova |
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Affiliation: | Institute of Chemistry of Solution Russian Academy of Sciences, Ivanovo 153045, Akademicheskaya ul., 1, Russia |
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Abstract: | It is evident that the solvent effect on tetracene oxidation by singlet molecular oxygen is predominantly conditioned by a specific solvation of the reaction intermediate in aprotic media that is assumed to be a state with a stressed anionic center. |
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Keywords: | tetracene oxidation singlet oxygen specific solvation intermediate |
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