A new strategy for the synthesis of α,β-diaroylpropionates promoted by samarium metal in DMF |
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| Authors: | Yongjun LiuXi Liu Yongmin Zhang |
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| Affiliation: | a Department of Chemistry, Zhejiang University (Campus Xixi), Hangzhou 310028, PR China
b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, PR China |
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| Abstract: | When promoted by samarium in DMF, aroyl chlorides react readily with acrylates to afford α,β-diaroylpropionates in good to excellent yields without pretreating or activating the metallic samarium. |
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| Keywords: | samarium DMF aroyl chloride acrylate α,β-diaroylpropionate |
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