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Preparation and evaluation of novel chiral stationary phases covalently bound with chiral pseudo-18-crown-6 ethers
Authors:Keiji Hirose  Takashi NakamuraRyota Nishioka  Tetsuro UeshigeYoshito Tobe
Affiliation:a Department of Chemistry, Faculty of Engineering Science, Osaka University, Machikaneyama, Toyonaka, Osaka 560-8531, Japan
b Sumika Chemical Analysis Service, 3-1-135 Kasugadenaka, Konohana, Osaka 554-0022, Japan
Abstract:Novel chiral stationary phases consisting of silica gel covalently bound with chiral pseudo-18-crown-6 type hosts, which possess either an OH or OMe group as a binding functionality, were prepared for enantiomer-separation of lipophilic amines.
Keywords:chiral stationary phase   crown ether   chiral recognition
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